Fist of all, welcome to the forum!
Looks like you are close to the beginning of your
cycle. Either that or your bacteria colonies are a little out of whack. The thing to keep the closest eye on at this point is the
Ammonia level.
Ammonia should be 0 before you put any more fish into the tank. I'm surprised the guppy is still alive with
ammonia that high. The
Nitrite looks good, but it should rise higher than 0 once the
Ammonia begins to fall. Just as a primer or review (whichever the case may be) waste and decomposing materials produce/become
Ammonia.
Ammonia is broken down by a bacteria colony to become
Nitrite.
Nitrite is broken down by a second bacteria colony to become
Nitrate.
Nitrate is the least toxic of the three and is generally removed by performing water changes. A tank is considered "cycled" once the
Ammonia and
Nitrite levels have fallen back to 0 from whatever they were at the beginning of the
cycle.
One thing to keep in mind about cycling is that you have to be careful and take your time stocking your tank. Just because your tank has cycled with one fish doesn't mean the bacteria colonies are robust enough to handle 5 fish. I made this mistake with my first freshwater tank and lost quite a few nice fish. Be patient and keep up the good work and you'll have a tank full of beautiful fish before you know it. :)
No trees were harmed in the writing of this post. However, several electrons were GREATLY inconvenienced.
"If nobody makes you do it, it counts as fun." --Hobbes the Tiger